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In addition to being a precursor for glutathione synthesis, and the principal methyl donor for nucleic acid, phospholipid, histone, biogenic amine, and protein methylation, methionine metabolites can participate in polyamine synthesis

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Throughout this process, the tumor cells produce a group of signaling molecules known as damage-associated molecular patterns (DAMPs) (44), including calreticulin (CRT) that exposes on the cell surface, secreted ATP, heat shock proteins (HSP70 and HSP90), and high mobility group protein 1 (HMGB1) ( Figure 3 )